HRID1589608

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8125

1-Octene

C8H16

HCID87780

Silane, trioctyl-

C24H52Si

PRODUCTS

生成物

结构：CCCCCCCC[Si](CCCCCCCC)(CCCCCCCC)CCCCCCCC

HCID620432

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

结构：[Cl-].[Rh].c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1.c1ccc(P(c2ccccc2)c2ccccc2)cc1

催化剂HCID84599

未命名化合物

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

A mixture of 2.0 grams trioctylsilane and 10 grams 1-octene in 5 milliliters of toluene was reacted for 2 hours at 75°-80° C. in the presence of 0.009 gram of chlorotris(triphenylphosphine)rhodium(I) to yield 80 weight percent tetraoctylsilane.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-05abb628ee924f70bb05e14d3ac0d84c
来源数据集: uspto-grants-1986_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04572791
来源说明: uspto-grants-1986_02

反应 SMILES

[CH2:1]([SiH:9]([CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH2:26]=[CH:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33]>C1(C)C=CC=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1C=CC(P(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.[Cl-].[Rh]>[CH2:18]([Si:9]([CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH3:33])([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]