N,N-Dimethylethylenediamine → HCID 69433451, compound

HRID 1593432Notes

Reaction equation

HRID 1593432 reaction equation
CS([C:5]1[N:10]=[CH:9][C:8]([C:11]2[O:15][C:14]([C:16]3[CH:21]=[CH:20][N:19]=[CH:18][CH:17]=3)=[C:13]([C:22]3[CH:23]=[C:24]4[C:28](=[CH:29][CH:30]=3)[C:27](=[O:31])[CH2:26][CH2:25]4)[CH:12]=2)=[CH:7][N:6]=1)(=O)=O.[CH3:32][N:33]([CH3:37])[CH2:34][CH2:35][NH2:36]>>[CH3:32][N:33]([CH3:37])[CH2:34][CH2:35][NH:36][C:5]1[N:10]=[CH:9][C:8]([C:11]2[O:15][C:14]([C:16]3[CH:17]=[CH:18][N:19]=[CH:20][CH:21]=3)=[C:13]([C:22]3[CH:23]=[C:24]4[C:28](=[CH:29][CH:30]=3)[C:27](=[O:31])[CH2:26][CH2:25]4)[CH:12]=2)=[CH:7][N:6]=1

Participants

3

Reactant 2

HCID 66053N,N-DimethylethylenediamineHCID 69430943HCID 69430943, compound

Product 1

HCID 69433451HCID 69433451, compoundYield 20%

Procedure

The title compound (0.03 g, 20%) was prepared from the product of Example 7 Step 6 and N,N-dimethylethylenediamine using the method of Example 7 Step 7; 1H NMR (CDCl3) 8.68 (2H, s), 8.52 (2H, d, J 8 Hz), 7.82 (1H, d, J 10 Hz), 7.57 (H, s), 7.46 (1H, d, J 10 Hz), 7.39 (2H, J 8 Hz), 6.67 (1H, s), 5.90 (1H, m), 3.53 (2H, m), 3.18 (2H, t, J 5 Hz), 2.77 (2H, t, J 8 Hz,), 2.56 (2H, t, J 5 Hz) 2.29 (6H, s).

Sources & evidence

ORD record
ord-cea97e32f2f54b789c4d4e259acf1a9a
Source dataset
uspto-grants-2007_11
Patent number
US07297694B2

Reaction notes

Loading…