Acetic Acid → HCID 18923982, compound

HRID 1600131Notes

Reaction equation

HRID 1600131 reaction equation
COC1C=CC(C[S:10][CH:11]2[CH2:15][S:14](=[O:17])(=[O:16])[CH:13]([CH2:18][OH:19])[CH2:12]2)=CC=1.C1(OC)C=CC=CC=1.C(O)(=O)C>C(OCC)(=O)C.CCCCCC>[SH:10][CH:11]1[CH2:15][S:14](=[O:17])(=[O:16])[CH:13]([CH2:18][OH:19])[CH2:12]1

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 7519AnisoleHCID 67707349HCID 67707349, compound

Product 1

HCID 18923982HCID 18923982, compoundYield 86.9%

Reagents, catalysts & solvents 1

HCID 21226206Ethyl acetate hexaneSolvent

Procedure

The title compound is prepared by the procedure of Example 202 using 0.615 g of product from Example 177, 1.04 g of mercuric trifluoroacetate, 0.440 g of anisole and 31 ml of 80% acetic acid to give, after chromatography (Silica gel: 10-100% ethyl acetate/hexane), 0.322 g of the desired product.

Workup

  1. customto give

Sources & evidence

ORD record
ord-72bd509072b8410d84e0f8fe1f034498
Source dataset
uspto-grants-1998_04
Patent number
US05744465

Reaction notes

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