Sodium hydride → HCID 23700988, compound

HRID 1600848Notes

Reaction equation

HRID 1600848 reaction equation
[CH2:1]1[O:5][C:4]2[CH:6]=[C:7]([OH:10])[CH:8]=[CH:9][C:3]=2[O:2]1.[H-].[Na+:12]>C1COCC1>[CH2:1]1[O:2][C:3]2[CH:9]=[CH:8][C:7]([O-:10])=[CH:6][C:4]=2[O:5]1.[Na+:12]

Participants

4

Reactant 2

HCID 24758Sodium hydrideHCID 68289Sesamol

Product 1

HCID 23700988HCID 23700988, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
25 °C

Procedure

Sesamol (415 mg, 3.0 mmol) was added, as a solution in THF (2 ml), to a suspension of mineral oil-free NaH under a water cooling bath. The mixture was stirred at 25° C. for 20 min. yielding a clear solution. The solvent was evaporated at 40° C. under reduced pressure and the resulting solid sodium 3,4-(methylenedioxy)phenoxide was dried in vacuo at 25° C. for 30 min before use.

Workup

  1. customyielding a clear solution
  2. customThe solvent was evaporated at 40° C. under reduced pressure
  3. dry with materialthe resulting solid sodium 3,4-(methylenedioxy)phenoxide was dried in vacuo at 25° C. for 30 min before use

Sources & evidence

ORD record
ord-6c162899d5894ef08408248c8e2e2bc5
Source dataset
uspto-grants-1999_11
Patent number
US05977117

Reaction notes

Loading…