Aniline → Sulfuric Acid
Reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.NC1C=C([S:15]([OH:18])(=[O:17])=[O:16])C=CC=1.NC1C=CC(S(O)(=O)=[O:27])=CC=1.NC1C=CC=CC=1S(O)(=O)=O>>[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[S:15](=[O:16])(=[O:27])([OH:17])[OH:18]Participants
Procedure
As a method for the synthesis of a sulfonated polyaniline, there are known, for example, a method for the synthesis of a sulfonated polyaniline by electrochemically polymerizing aniline and m-aminobenzenesulfonic acid (Journal of The Chemical Society of Japan, 1985, 1124 and JA-A-2-166,165), a method for the synthesis of a sulfonated polyaniline by electrochemically polymerizing an o-, m- or p-aminobenzenesulfonic acid alone [Lecture Preprint II in the 64th Autumn Annual Convention of The Chemical Society of Japan, 706 (1992)], a method for the synthesis of a sulfonated polyaniline by chemically polymerizing aniline and an o- or m-aminobenzenesulfonic acid (JP-A-1-301,714), a method for the chemical oxidation polymerization of an aminobenzenesulfonic acid compound or monomers comprising an aminobenzenesulfonic acid compound and an aniline compound (JP-A-6-56,987), a method for the sulfonation with conc. sulfuric acid of an emeraldine type polymer (polyaniline) obtained by chemical or electrochemical polymerization (JP-A-58-210,902), a method for the sulfonation with sulfuric anhydride/triethyl phosphate complex (JP-A-61-197,633), a method for the sulfonation with fuming sulfuric acid [J. Am. Chem. Soc., (1991) 113, 2665-2671, J. Am. Chem. Soc., (1990) 112, 2800 and WO91-06887], a method for the synthesis of a sulfonated polyaniline of the N-substitution type by chemically polymerizing diphenylamine-4-sulfonic acid (sodium salt) [Polymer, (1993) 34, 158-162] and the like.
Sources & evidence
- ORD record
- ord-f8f166bc9cb9427eb25f1865a72df09a
- Source dataset
- uspto-grants-1999_11
- Patent number
- US05980784
Reaction notes
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