Hydrogen Peroxide → Nickel nitrate

HRID 1602038Notes

Reaction equation

HRID 1602038 reaction equation
[Ni:1].[Li].[Li].[CH:4]([O-:6])=[O:5].[Li+:7].[N+:8]([O-:11])([O-:10])=[O:9].[Li+].[N+:13]([O-:16])([O-:15])=[O:14].[Ni+2].[N+:18]([O-:21])([O-:20])=[O:19].[N+]([O-])(O)=O.OO.O=O>O>[N+:8]([O-:11])([O-:10])=[O:9].[Li+:7].[CH:4]([O-:6])=[O:5].[Ni+2:1].[CH:4]([O-:6])=[O:5].[N+:13]([O-:16])([O-:15])=[O:14].[Ni+2:1].[N+:18]([O-:21])([O-:20])=[O:19]

Participants

12

Reactant 8

HCID 784Hydrogen Peroxide2×HCID 944Nitric Acid2×HCID 977Oxygen2×HCID 25736Nickel nitrate2×HCID 3028194LithiumHCID 10129889Lithium nitrateHCID 23680280Lithium formate2×HCID 57507840Lithium nickel

Product 3

HCID 25736Nickel nitrateHCID 27506Formic acid, nickel saltHCID 10129889Lithium nitrate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent3×

Procedure

First, lithium nitrate, nickel formate, and nickel nitrate were prepared as the compounds of metal elements constituting the lithium nickel complex oxide as the cathode active material for a lithium secondary battery, lithium formate,. Then, 1.0 mol of lithium formate or lithium nitrate and 1.0 mol of nickel nitrate or nickel nitrate were precisely weighed, placed in a vessel, and after adding thereto 4,950 ml of water and 50 ml of nitric acid having a concentration of 60% and a specific gravity of 1.38 or 4,900 ml of water and 100 ml of hydrogen peroxide or 5,000 ml of water only, the mixture was stirred to dissolve the salts. The nitric acid or hydrogen peroxide is a material generating oxygen at the spray pyrolysis, that is, an oxygen-generating material.

Workup

  1. customplaced in a vessel
  2. additionafter adding
  3. dissolutionto dissolve the salts

Sources & evidence

ORD record
ord-967ec1deb18442c092b09104deeb4b52
Source dataset
uspto-grants-1999_11
Patent number
US05980786

Reaction notes

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