Ethanol → HCID 19610575, compound

HRID 1602264Notes

Reaction equation

HRID 1602264 reaction equation
CS[C:3]([S:9][CH3:10])=[C:4]([C:7]#[N:8])[C:5]#[N:6].[CH3:11][O:12][C:13]1[CH:20]=[CH:19][C:16]([CH2:17][NH2:18])=[CH:15][CH:14]=1.C(O)C>CCCCCC>[C:5]([C:4](=[C:3]([NH:18][CH2:17][C:16]1[CH:19]=[CH:20][C:13]([O:12][CH3:11])=[CH:14][CH:15]=1)[S:9][CH3:10])[C:7]#[N:8])#[N:6]

Participants

5

Reactant 3

HCID 702EthanolHCID 754524-MethoxybenzylamineHCID 992292-(Bis(methylsulfanyl)methylidene)propanedinitrile

Product 1

HCID 19610575HCID 19610575, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A mixture of 17.03 g (0.1 mol) of 3,3-bis-methylmercapto-2-cyano-acrylonitrile, 12.98 ml (0.1 mol) of 4-methoxy-benzylamine and 60 ml of ethanol is heated under reflux for 2 hours. Approx. 90 ml of hexane are then added dropwise to the hot solution which is then allowed to cool to RT. The title compound which has precipitated in the form of colorless crystals is filtered off, washed with diethyl ether and dried under a HV; m.p. 100-101° C.

Workup

  1. temperatureis heated
  2. temperatureunder reflux for 2 hours
  3. customThe title compound which has precipitated in the form of colorless crystals
  4. filtrationis filtered off
  5. washwashed with diethyl ether
  6. customdried under a HV

Sources & evidence

ORD record
ord-4c89c6156c834c649b6a0d3f7b08071c
Source dataset
uspto-grants-1999_11
Patent number
US05981533

Reaction notes

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