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HRID1603879

反应详情

EQUATION

反应方程式

HRID 1603879 的结构方程式

REACTANTS

反应物

2
结构：CCOC(=O)C(=O)OCC
HCID7268

Diethyl oxalate

C6H10O4

结构：CC(=O)c1cc(Br)cc([N+](=O)[O-])c1O
HCID689071

1-(5-Bromo-2-hydroxy-3-nitrophenyl)ethan-1-one

C8H6BrNO4

PRODUCTS

生成物

1
结构：CCOC(=O)c1cc(=O)c2cc(Br)cc([N+](=O)[O-])c2o1
HCID19606344

未命名化合物

收率 77%

PROCEDURE

实验过程

Following the process described in example 1 (point A), starting from 5-bromo-2-hydroxy-3-nitroacetophenone and diethyl oxalate, the title compound was prepared, which was purified by crystallization in tetrahydrofuran:ethanol mixtures (77% yield).

WORKUP

后处理

  1. customwhich was purified by crystallization in tetrahydrofuran