Potassium Acetate → HCID 21548931, compound

HRID 1605055Notes

Reaction equation

HRID 1605055 reaction equation
BrC(C1C=CC2OC3C(=CC=CC=3)CC=2C=1)CC.C([O-])(=O)C.[K+].C(O[CH2:28][CH:29]([C:31]1[CH:44]=[CH:43][C:42]2[O:41][C:40]3[C:35](=[CH:36][CH:37]=[CH:38][CH:39]=3)[CH2:34][C:33]=2[CH:32]=1)[CH3:30])(=O)C>CN(C=O)C>[CH:32]1[C:33]2[CH2:34][C:35]3[C:40](=[CH:39][CH:38]=[CH:37][CH:36]=3)[O:41][C:42]=2[CH:43]=[CH:44][C:31]=1[C:29]([CH3:30])=[CH2:28]

Participants

5

Reactant 3

HCID 517044Potassium AcetateHCID 21548955HCID 21548955, compoundHCID 21548988HCID 21548988, compound

Product 1

HCID 21548931HCID 21548931, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

3 g. of 1-bromo-(2-xanthenyl)-propane is dissolved in 20 ml. of DMF, mixed with 3 g. of anhydrous potassium acetate, and stirred for 3 hours at 60°. The mixture is worked up as usual, thus obtaining 2-(2-xanthenyl)-propyl acetate, m.p. 62°-64°. Additionally, a small amount of 2-(2-xanthenyl)-propene is produced.

Sources & evidence

ORD record
ord-d5c9b5c10a8647c4aeb1d3fa22fbce2f
Source dataset
uspto-grants-1976_04
Patent number
US03948949

Reaction notes

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