Chloroform → HCID 21549140, compound

HRID 1605112Notes

Reaction equation

HRID 1605112 reaction equation
[CH3:1][C:2]([CH3:12])=[CH:3][C:4]1[CH:9]=[CH:8][C:7]([O:10][CH3:11])=[CH:6][CH:5]=1.CC(C)([O-])C.[K+].[CH:19]([Cl:22])(Cl)[Cl:20]>CCCCC>[Cl:20][C:19]1([Cl:22])[C:2]([CH3:12])([CH3:1])[CH:3]1[C:4]1[CH:5]=[CH:6][C:7]([O:10][CH3:11])=[CH:8][CH:9]=1

Participants

5

Reactant 3

HCID 6212ChloroformHCID 11321128Benzene, 1-methoxy-4-(2-methyl-1-propenyl)-HCID 23665647Potassium tert-butoxide

Product 1

HCID 21549140HCID 21549140, compound

Reagents, catalysts & solvents 1

HCID 8003PentaneSolvent

Procedure

p-(2,2-Dichloro-3,3-dimethylcyclopropyl)anisole was prepared from 58.3 g. of p-(2,2-dimethylvinyl)anisole, 102 g. of potassium t-butoxide, 180 ml. of chloroform and 1800 ml. of pentane according to the procedure described above in Example 1, part (b). The product was recrystallized from hexane to produce p-(2,2-dichloro-3,3-dimethylcyclopropyl)anisole in the form of colorless needles, m.p. 54.5°-57°C.

Workup

  1. customp-(2,2-Dichloro-3,3-dimethylcyclopropyl)anisole was prepared from 58.3 g
  2. customThe product was recrystallized from hexane

Sources & evidence

ORD record
ord-d34481a1029547a791d15722cd32c746
Source dataset
uspto-grants-1976_04
Patent number
US03948973

Reaction notes

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