Hydrogen Peroxide → Dipropyl peroxydicarbonate

HRID 1605407Notes

Reaction equation

Cl[C:2]([O:4][CH2:5][CH2:6][CH3:7])=[O:3].[OH:8][OH:9].[OH-:10].[Na+].[Na+].[Cl-]>>[CH2:5]([O:4][C:2]([O:8][O:9][C:2]([O:4][CH2:5][CH2:6][CH3:7])=[O:10])=[O:3])[CH2:6][CH3:7]

Participants

Reactant 4

HCID 784Hydrogen Peroxide

HCID 5234Sodium Chloride

HCID 7998Propyl chloroformate

HCID 14798Sodium Hydroxide

Product 1

HCID 85264Dipropyl peroxydicarbonate

Procedure

Using the apparatus (i.e., both centrifuges 18 and 30) and procedure of Example I (except that the temperature of reactor 14 is 25 ± 1° C.), NPP is prepared at the rate of 50 pph in an average assay of greater than 98% from 85 pph of n-propyl chloroformate, 31 pph of 50% aqueous H2O2, 169 pph of 20% NaOH and 50 pph of saturated NaCl solution.

Workup

customboth centrifuges 18 and 30) and procedure of Example I (except that the temperature of reactor 14 is 25 ± 1° C.

Sources & evidence

ORD record: ord-195b029a725b461bac802e58a9d720c1
Source dataset: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03950375

Reaction notes

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