Dimetridazole → HCID 327488, compound

HRID 1606025Notes

Reaction equation

HRID 1606025 reaction equation
[N+:1]([C:4]1[N:8]([CH3:9])[C:7]([CH3:10])=[N:6][CH:5]=1)([O-:3])=[O:2].[CH3:11][N:12]([CH:14](N(C)C)OC(C)(C)C)[CH3:13]>CN(C)C=O>[N+:1]([C:4]1[N:8]([CH3:9])[C:7]([CH:10]=[CH:11][N:12]([CH3:14])[CH3:13])=[N:6][CH:5]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 3090DimetridazoleHCID 79885tert-Butoxy bis(dimethylamino)methane

Product 1

HCID 327488HCID 327488, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

14.1 g. (0.1 mole) of 5-nitro-1,2-dimethylimidazole and 21 g. (0.12 mole) of bis-dimethylamino-tert.-butoxymethane were heated in 90 ml. of dimethylformamide to 130° C. for 15 minutes. After cooling, the red crystals were vacuum-filtered and recrystallized from dimethylformamide.

Workup

  1. temperatureAfter cooling
  2. filtrationthe red crystals were vacuum-filtered
  3. customrecrystallized from dimethylformamide

Sources & evidence

ORD record
ord-ef8209a719824f259c54cc6763cc1889
Source dataset
uspto-grants-1976_04
Patent number
US03952007

Reaction notes

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