Ethanol → HCID 21546446, compound

HRID 1606315Notes

Reaction equation

HRID 1606315 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([CH2:9][CH2:10]O)=[CH:5][CH:4]=1.[Na].C([OH:15])C>N>[OH:15][CH:9]([C:6]1[CH2:5][CH:4]=[C:3]([O:2][CH3:1])[CH2:8][CH:7]=1)[CH3:10]

Participants

5

Reactant 3

HCID 702EthanolHCID 697054-Methoxyphenethyl alcoholHCID 5360545Sodium

Product 1

HCID 21546446HCID 21546446, compound

Reagents, catalysts & solvents 1

HCID 222AmmoniaSolvent

Procedure

A solution of 40 g of 2-(4-methoxyphenyl)ethanol in 80 ml of ethanol and 800 ml of ammonia reduced with 30.4 g of sodium to yield 27.4 g, bp 87°-89° (0.7 mm), identified by nmr.

Workup

  1. customto yield 27.4 g, bp 87°-89° (0.7 mm)

Sources & evidence

ORD record
ord-57ac1f9560484fcfa1efda0b286a556a
Source dataset
uspto-grants-1976_04
Patent number
US03952114

Reaction notes

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