Hydrochloric Acid → HCID 12201323, compound

HRID 1606387Notes

Reaction equation

HRID 1606387 reaction equation
[NH2:1][C:2]([NH2:4])=[O:3].Cl.[Cl:6]([O-:10])(=[O:9])(=[O:8])=[O:7].[Na+]>>[Cl:6]([OH:10])(=[O:9])(=[O:8])=[O:7].[NH2:1][C:2]([NH2:4])=[O:3]

Participants

4

Reactant 3

HCID 313Hydrochloric AcidHCID 1176UreaHCID 522606Sodium Perchlorate

Product 1

HCID 12201323HCID 12201323, compound

Conditions

Temperature
40 °C

Procedure

606 Grams of urea were added to 1040 g of 35% hydrochloric acid and dissolved therein under agitation. Then, 1405 g of sodium perchlorate were added to the solution and the mixture was stirred vigorously for 10 minutes at 40°C and cooled to 20°C. The precipitated crystals were separated by filtration. These crystals were sodium chloride. The filtrate contained about 65% of urea perchlorate but still contained a small amount of sodium chloride dissolved therein. Thus, the filtrate was concentrated under reduced pressure at a temperature below 80°C and filtered while hot, thereby removing the majority of the sodium chloride. By repeating this procedure comprising concentration and cooling for the aqueous solution of urea perchlorate thus obtained, crystals of urea perchlorate could be produced in a high yield.

Workup

  1. dissolutiondissolved
  2. temperaturecooled to 20°C
  3. customThe precipitated crystals were separated by filtration
  4. dissolutiondissolved
  5. concentrationThus, the filtrate was concentrated under reduced pressure at a temperature below 80°C
  6. filtrationfiltered while hot,
  7. customthereby removing the majority of the sodium chloride
  8. concentrationthis procedure comprising concentration
  9. temperaturecooling for the aqueous solution of urea perchlorate
  10. customthus obtained

Sources & evidence

ORD record
ord-cb30042831d24b5680478b3fed6bd262
Source dataset
uspto-grants-1976_04
Patent number
US03952655

Reaction notes

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