Phenol → HCID 131716103, compound

HRID 1607343Notes

Reaction equation

HRID 1607343 reaction equation
Cl[P:2]1([O:26][C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=2[NH2:33])[N:7]=[P:6](Cl)([O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[NH2:15])[N:5]=[P:4](Cl)([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=2[NH2:24])[N:3]=1.ClP1(Cl)N=P(Cl)(Cl)N=P(Cl)(Cl)N=1.[C:46]1([OH:52])[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=1.[H-].[Na+]>C1COCC1>[O:52]([P:2]1([O:26][C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=2[NH2:33])[N:7]=[P:6]([O:8][C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)([O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[NH2:15])[N:5]=[P:4]([O:17][C:18]2[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=2)([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=2[NH2:24])[N:3]=1)[C:46]1[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=1

Participants

6

Reactant 4

HCID 996PhenolHCID 24758Sodium hydrideHCID 220225HexachlorocyclotriphosphazeneHCID 131716104HCID 131716104, compound

Product 1

HCID 131716103HCID 131716103, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The procedure of Example 6 was used, with a sample of trichloro-tris(aminophenoxy)cyclotriphosphazene, prepared as in Example 4, as the starting phosphazene reagent. The reagent amounts were: hexachlorocyclotriphosphazene, 0.05 mole; phenol, 0.21 mole; sodium hydride, 0.22 mole. The product was isolated as an amber oil, which contained traces of THF.

Workup

  1. customThe product was isolated as an amber oil, which

Sources & evidence

ORD record
ord-ff214651dc6640ca96e8f76a30353086
Source dataset
uspto-grants-1989_09
Patent number
US04864047

Reaction notes

Loading…