Ozone → HCID 13933696, compound

HRID 1607355Notes

Reaction equation

HRID 1607355 reaction equation
[O:1]=[O+][O-].[CH3:4][C:5]1([CH3:27])[CH:7]([CH:8]=C(C)C)[CH:6]1[C:12]([O:14][CH2:15][C:16]1[C:21]([F:22])=[C:20]([F:23])[C:19]([F:24])=[C:18]([F:25])[C:17]=1[F:26])=[O:13]>C(OCC)(=O)C>[CH3:4][C:5]1([CH3:27])[CH:7]([CH:8]=[O:1])[CH:6]1[C:12]([O:14][CH2:15][C:16]1[C:21]([F:22])=[C:20]([F:23])[C:19]([F:24])=[C:18]([F:25])[C:17]=1[F:26])=[O:13]

Participants

4

Reactant 2

HCID 24823OzoneHCID 13933695HCID 13933695, compound

Product 1

HCID 13933696HCID 13933696, compoundYield 89%

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Ozone gas was bubbled at -78° C. into a solution of 3.48 g (10.0 mmol) of pentafluorophenylmethyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate obtained in Reference Example 4, in 20 ml of ethyl acetate. The subsequent operation was conducted in the same manner as in Reference Example 5, whereby 2.87 g of pentafluorophenylmethyl 2,2-dimethyl-3-formylcyclopropanecarboxylate was obtained as a colorless oil.

Sources & evidence

ORD record
ord-2458a32ff73e44b1827b5ba7e2aaa925
Source dataset
uspto-grants-1989_09
Patent number
US04864052

Reaction notes

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