4-Methylbenzyl alcohol → HCID 20084145, compound

HRID 1609169Notes

Reaction equation

HRID 1609169 reaction equation
[CH3:1][C:2]1[CH:9]=[CH:8][C:5]([CH2:6]O)=[CH:4][CH:3]=1.[F:10][Sb-:11]([F:16])([F:15])([F:14])([F:13])[F:12].[CH3:17][N:18]([CH3:25])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>[N+](C)([O-])=O>[F:10][Sb-:11]([F:16])([F:15])([F:14])([F:13])[F:12].[CH3:1][C:2]1[CH:9]=[CH:8][C:5]([CH2:6][N+:18]([CH3:25])([CH3:17])[C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 115054-Methylbenzyl alcoholHCID 86748579HCID 86748579, compound

Product 1

HCID 20084145HCID 20084145, compoundYield 55%

Reagents, catalysts & solvents 1

HCID 6375NitromethaneSolvent

Procedure

12.21 g (0.1 mol) of 4-methylbenzylalcohol and 35.78 g (0.1 mol) of N,N-dimethylaniline hexafluoroantimonate were dissolved in 100 g of nitromethane and allowed to react at 80° C. for 8 hours. After the completion of the reaction, the mixture was concentrated, and the precipitated white solid was washed with ether and dried to give the titled compound. Yield: 55%.

Workup

  1. customto react at 80° C. for 8 hours
  2. customAfter the completion of the reaction
  3. concentrationthe mixture was concentrated
  4. washthe precipitated white solid was washed with ether
  5. customdried

Sources & evidence

ORD record
ord-8d992ad8746b4335b2d86ada8e628895
Source dataset
uspto-grants-1995_03
Patent number
US05399695

Reaction notes

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