HRID1611420

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6547

Azobisisobutyronitrile

C8H12N4

HCID7923

2,5-Furandione

C4H2O3

HCID98465

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid, 2-methyl ester

C10H12O4

HCID9964188

未命名化合物

HCID15607334

Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 1,1-dimethylethyl ester

C12H18O2

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)C1CC2C=CC1C2.COC(=O)C1C2C=CC(C2)C1C(=O)O.O=C(O)C1CC2C=CC1C2.O=C1C=CC(=O)O1.O=C1OC(=O)C2C1[C@@H]1C=C[C@H]2C1

HCID131723902

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

Maleic anhydride (1.0 mole), cis-5-norbornene-endo-2,3-dicarboxylic anhydride (0.2 mole), mono-methyl cis-5-norbornene-endo-2,3-dicarboxylate (0.15 mole) and tert-butyl-5-norbornene-2-carboxylate (0.65 mole) are dissolved in tetrahydrofuran. Then, 0.5 to 10 g of AIBN (azobisisobutyronitrile) as a polymerization initiator is added thereto, and the resultant mixture is reacted at about 60-70° C. for 4 to 24 hours under nitrogen or argon atmosphere. The polymer thus obtained is precipitated from ethyl ether or hexane, and dried to obtain the compound represented by the following Chemical Formula 101.

WORKUP

后处理

customThe polymer thus obtained
customis precipitated from ethyl ether or hexane
customdried
customto obtain the compound

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c1bc7c4a979845838d0d71f4f84a1cf1
来源数据集: uspto-grants-2006_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06987155B2
来源说明: uspto-grants-2006_01

反应 SMILES

[C:1]1(=[O:7])[O:6][C:4](=[O:5])[CH:3]=[CH:2]1.[CH2:8]1[C@@H:12]2[CH:13]3[C:18](=[O:19])[O:17][C:15](=[O:16])[CH:14]3[C@H:9]1[CH:10]=[CH:11]2.[CH3:20][O:21][C:22]([CH:24]1[CH:28]([C:29]([OH:31])=[O:30])[CH:27]2[CH:32]=[CH:33][CH:25]1[CH2:26]2)=[O:23].[C:34]([O:38][C:39]([CH:41]1[CH2:46][CH:45]2[CH2:47][CH:42]1[CH:43]=[CH:44]2)=[O:40])([CH3:37])([CH3:36])[CH3:35].N(C(C)(C)C#N)=NC(C)(C)C#N>O1CCCC1>[CH2:8]1[C@@H:12]2[CH:13]3[C:18](=[O:19])[O:17][C:15](=[O:16])[CH:14]3[C@H:9]1[CH:10]=[CH:11]2.[CH:42]12[CH2:47][CH:45]([CH:44]=[CH:43]1)[CH2:46][CH:41]2[C:39]([O:38][C:34]([CH3:37])([CH3:36])[CH3:35])=[O:40].[C:4]1(=[O:5])[O:6][C:1](=[O:7])[CH:2]=[CH:3]1.[CH3:20][O:21][C:22]([CH:24]1[CH:28]([C:29]([OH:31])=[O:30])[CH:27]2[CH:32]=[CH:33][CH:25]1[CH2:26]2)=[O:23].[CH:9]12[CH2:8][CH:12]([CH:11]=[CH:10]1)[CH2:13][CH:14]2[C:15]([OH:17])=[O:16]