Aluminium lithium hydride → HCID 22252351, compound

HRID 1611990Notes

Reaction equation

HRID 1611990 reaction equation
[H-].[H-].[H-].[H-].[Li+].[Al+3].[CH2:7]1[N:12]([CH2:13][CH2:14][C:15](OCC)=[O:16])[CH2:11][CH2:10][N:9]2[CH2:20][CH2:21][CH2:22][CH2:23][CH:8]12>O1CCCC1>[CH2:7]1[N:12]([CH2:13][CH2:14][CH2:15][OH:16])[CH2:11][CH2:10][N:9]2[CH2:20][CH2:21][CH2:22][CH2:23][CH:8]12

Participants

4

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 22252333HCID 22252333, compound

Product 1

HCID 22252351HCID 22252351, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

1 g of LiAlH4 is added in portions to a solution of 3 g of the compound obtained in Step A, in 100 ml of tetrahydrofuran, and then the reaction mixture is stirred for 8 hours, subsequently hydrolysed, filtered and finally evaporated to dryness.

Workup

  1. filtrationsubsequently hydrolysed, filtered
  2. customfinally evaporated to dryness

Sources & evidence

ORD record
ord-db11236c17054f20b48eda3afa28bac8
Source dataset
uspto-grants-2006_01
Patent number
US06992085B2

Reaction notes

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