HRID1628368

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10340

Carbonic acid sodium salt (1:2)

CNa2O3

HCID2734393

4-Vinylphenylboronic acid

C8H9BO2

结构：Brc1ccc(-c2nc(-c3ccc(-c4ccccc4)cc3)nc(-c3ccc(-c4ccccc4)cc3)n2)cc1

HCID67335276

未命名化合物

PRODUCTS

生成物

结构：C=Cc1ccc(-c2ccc(-c3nc(-c4ccc(-c5ccccc5)cc4)nc(-c4ccc(-c5ccccc5)cc4)n3)cc2)cc1

HCID59439788

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

结构：c1ccc([P](c2ccccc2)(c2ccccc2)[Pd]([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[P](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

催化剂HCID178418397

未命名化合物

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

1.0 g (0.00185 mol) of 2,4-bisbiphenyl-4-yl-6-(4-bromophenyl)-1,3,5-triazine, 0.4106 g of 4-vinylphenylboronic acid and 0.02368 g of Pd(PPh3)4 are brought to reaction under reflux for 48 h with addition of 15 ml of 1M sodium carbonate solution and 30 ml of THF.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1e93f0e2168f4cb383a89eceeb4f025d
来源数据集: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08786181B2
来源说明: uspto-grants-2014_07

反应 SMILES

[C:1]1([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[CH:6]=[CH:5][C:4]([C:7]2[N:12]=[C:11]([C:13]3[CH:18]=[CH:17][C:16]([C:19]4[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=4)=[CH:15][CH:14]=3)[N:10]=[C:9]([C:25]3[CH:30]=[CH:29][C:28](Br)=[CH:27][CH:26]=3)[N:8]=2)=[CH:3][CH:2]=1.[CH:38]([C:40]1[CH:45]=[CH:44][C:43](B(O)O)=[CH:42][CH:41]=1)=[CH2:39].C(=O)([O-])[O-].[Na+].[Na+]>C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1COCC1>[C:1]1([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[CH:6]=[CH:5][C:4]([C:7]2[N:12]=[C:11]([C:13]3[CH:18]=[CH:17][C:16]([C:19]4[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=4)=[CH:15][CH:14]=3)[N:10]=[C:9]([C:25]3[CH:30]=[CH:29][C:28]([C:43]4[CH:44]=[CH:45][C:40]([CH:38]=[CH2:39])=[CH:41][CH:42]=4)=[CH:27][CH:26]=3)[N:8]=2)=[CH:3][CH:2]=1