Sodium Carbonate → 2,4-Bisbiphenyl-4-yl-6-(4'-vinylbiphenyl-4-yl)-1,3,5-triazine

HRID 1628368Notes

Reaction equation

HRID 1628368 reaction equation
[C:1]1([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[CH:6]=[CH:5][C:4]([C:7]2[N:12]=[C:11]([C:13]3[CH:18]=[CH:17][C:16]([C:19]4[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=4)=[CH:15][CH:14]=3)[N:10]=[C:9]([C:25]3[CH:30]=[CH:29][C:28](Br)=[CH:27][CH:26]=3)[N:8]=2)=[CH:3][CH:2]=1.[CH:38]([C:40]1[CH:45]=[CH:44][C:43](B(O)O)=[CH:42][CH:41]=1)=[CH2:39].C(=O)([O-])[O-].[Na+].[Na+]>C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1.C1COCC1>[C:1]1([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[CH:6]=[CH:5][C:4]([C:7]2[N:12]=[C:11]([C:13]3[CH:18]=[CH:17][C:16]([C:19]4[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=4)=[CH:15][CH:14]=3)[N:10]=[C:9]([C:25]3[CH:30]=[CH:29][C:28]([C:43]4[CH:44]=[CH:45][C:40]([CH:38]=[CH2:39])=[CH:41][CH:42]=4)=[CH:27][CH:26]=3)[N:8]=2)=[CH:3][CH:2]=1

Participants

6

Reactant 3

HCID 10340Sodium CarbonateHCID 27343934-Vinylphenylboronic acidHCID 673352762,4-Bisbiphenyl-4-yl-6-(4-bromophenyl)-1,3,5-triazine

Product 1

HCID 594397882,4-Bisbiphenyl-4-yl-6-(4'-vinylbiphenyl-4-yl)-1,3,5-triazine

Reagents, catalysts & solvents 2

HCID 178418397HCID 178418397, compoundCatalystHCID 8028TetrahydrofuranSolvent

Procedure

1.0 g (0.00185 mol) of 2,4-bisbiphenyl-4-yl-6-(4-bromophenyl)-1,3,5-triazine, 0.4106 g of 4-vinylphenylboronic acid and 0.02368 g of Pd(PPh3)4 are brought to reaction under reflux for 48 h with addition of 15 ml of 1M sodium carbonate solution and 30 ml of THF.

Sources & evidence

ORD record
ord-1e93f0e2168f4cb383a89eceeb4f025d
Source dataset
uspto-grants-2014_07
Patent number
US08786181B2

Reaction notes

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