Hydroxylamine → HCID 178447908, compound

HRID 1632917Notes

Reaction equation

HRID 1632917 reaction equation
[CH2:1]([O:3][C:4]1[CH:12]=[CH:11][C:10]([C@H:13]2[CH2:18][CH2:17][C@H:16]([CH2:19][CH2:20][CH3:21])[CH2:15][CH2:14]2)=[CH:9][C:5]=1[CH:6]=[N:7]O)[CH3:2].NO.C(OC(=O)C)(=O)C>O>[CH2:1]([O:3][C:4]1[CH:12]=[CH:11][C:10]([C@H:13]2[CH2:14][CH2:15][C@H:16]([CH2:19][CH2:20][CH3:21])[CH2:17][CH2:18]2)=[CH:9][C:5]=1[C:6]#[N:7])[CH3:2]

Participants

5

Reactant 3

HCID 787HydroxylamineHCID 7918Acetic AnhydrideHCID 178447910HCID 178447910, compound

Product 1

HCID 178447908HCID 178447908, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A mixture of 28.9 g of 2-ethoxy-5-(trans-4-propyl-cyclohexyl)-benzaldoxime (obtainable from the aldehyde and hydroxylamine) and 40 ml of acetic anhydride is heated until the exothermic reaction starts, and is then boiled for 20 minutes and poured into water to give 2-ethoxy-5-(trans-4-propyl-cyclohexyl)-benzonitrile of m.p. 32°.

Workup

  1. temperatureis heated until the exothermic reaction

Sources & evidence

ORD record
ord-e269fb783078497a82485d82d963fc4e
Source dataset
uspto-grants-1984_10
Patent number
US04478740

Reaction notes

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