Water → HCID 20439642, compound

HRID 1633191Notes

Reaction equation

HRID 1633191 reaction equation
[Cl:1][C:2]1[C:11]([O:12][C:13]2[CH:18]=[CH:17][C:16]([Cl:19])=[CH:15][CH:14]=2)=[CH:10][CH:9]=[C:8]([N+:20]([O-:22])=[O:21])[C:3]=1[NH:4][CH2:5][CH2:6]O.P(Cl)(Cl)(Cl)(Cl)[Cl:24].O.C(=O)(O)[O-].[Na+]>C1(C)C=CC=CC=1>[Cl:1][C:2]1[C:11]([O:12][C:13]2[CH:18]=[CH:17][C:16]([Cl:19])=[CH:15][CH:14]=2)=[CH:10][CH:9]=[C:8]([N+:20]([O-:22])=[O:21])[C:3]=1[NH:4][CH2:5][CH2:6][Cl:24]

Participants

6

Reactant 4

HCID 962WaterHCID 24819Phosphorus pentachlorideHCID 516892Sodium BicarbonateHCID 20439640HCID 20439640, compound

Product 1

HCID 20439642HCID 20439642, compoundYield 75.9%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

An amount of 4.5 gm of 2-chloro-3-(4-chlorophenoxy)-6-nitro-N-2-hydroxyethylaniline was dissolved in 40 ml of toluene and mixed with 2.9 gm of PCl5, spontaneous heating and gas generation taking place. After 30 minutes the mixture was shaken with water and sodium bicarbonate solution and is evaporated. 3.6 gm of a yellowy brown oil were obtained (76% of theory).

Workup

  1. temperaturespontaneous heating
  2. customis evaporated

Sources & evidence

ORD record
ord-fe2ea5881bec472c9b2a80fd8bc2e4bc
Source dataset
uspto-grants-1984_10
Patent number
USRE031717

Reaction notes

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