Ammonium Hydroxide → o-nitrobenzenesulfenamide

HRID 1633227Notes

Reaction equation

HRID 1633227 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[S:10]Cl)([O-:3])=[O:2].[OH-].[NH4+:13]>C(Cl)(Cl)(Cl)Cl>[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[S:10][NH2:13])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 14923Ammonium HydroxideHCID 243192-Nitrobenzenesulfenyl chloride

Product 1

HCID 350641o-nitrobenzenesulfenamide

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

50 grams of o-nitrobenzenesulfenyl chloride was added to carbon tetrachloride with stirring, followed by 50 milliliters of ammonium hydroxide over a one-minute period. The stirring was continued over 5 minutes to obtain an o-nitrobenzenesulfenamide intermediate which precipitated in the reaction mixture. The o-nitrobenzenesulfenamide intermediate was recovered by filtration and dried.

Sources & evidence

ORD record
ord-060deb2f1e804478a5a7e0f67e863868
Source dataset
uspto-grants-1984_10
Patent number
US04479953

Reaction notes

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