Hydrogen Peroxide → Hydrogen Peroxide

HRID 1633393Notes

Reaction equation

HRID 1633393 reaction equation
[CH:1]1([OH:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH:8][OH:9]>CO>[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH:8][OH:9]

Participants

5

Reactant 2

HCID 784Hydrogen Peroxide2×HCID 7966Cyclohexanol

Product 2

HCID 784Hydrogen PeroxideYield 90%HCID 7967Cyclohexanone

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

50 cc of methanol (40 g), 20 g of cyclohexanol, 6 cc of 36% w/v aqueous hydrogen peroxide and 3 g of catalyst are fed into a glass autoclave. After 4 hours at 88° C., 95.6% of the fed hydrogen peroxide has reacted. 5.6 g of cyclohexanone are obtained with an H2O2 yield of 90%.

Sources & evidence

ORD record
ord-7e9dd09177db4c8f9bb004870d6ec04d
Source dataset
uspto-grants-1984_10
Patent number
US04480135

Reaction notes

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