Acrylamide → n-Decylacrylamide Acrylamid

HRID 1636449Notes

Reaction equation

HRID 1636449 reaction equation
[CH2:1]([C:11](=[CH2:15])[C:12]([NH2:14])=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[C:16]([NH2:20])(=[O:19])[CH:17]=[CH2:18]>C(O)(C)C>[CH2:1]([C:11](=[CH2:15])[C:12]([NH2:14])=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[C:16]([NH2:20])(=[O:19])[CH:17]=[CH2:18]

Participants

4

Reactant 2

HCID 6579AcrylamideHCID 212758792-Methylidenedodecanamide

Product 1

HCID 21275878n-Decylacrylamide Acrylamid

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Conditions

Temperature
75 °C

Procedure

To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 mL of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammoniumethylacrylate chloride, 8.06 g of n-decylacrylamide, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for -15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.

Workup

  1. customTo a 500 mL round-bottom, three-neck flask fitted with a thermocouple
  2. temperaturereflux condenser
  3. customThe solution was purged with nitrogen for 1 hour
  4. addition0.5 g AIBN was added
  5. customThe mixture was purged for -15 minutes until all of the AIBN
  6. dissolutiondissolved

Sources & evidence

ORD record
ord-cfaf9d45407542109e78203782f6f65e
Source dataset
uspto-grants-2000_03
Patent number
US06034129

Reaction notes

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