Hydrochloric Acid → HCID 18692792, compound

HRID 1636841Notes

Reaction equation

HRID 1636841 reaction equation
[OH:1][CH2:2][CH2:3][CH2:4][N:5]([CH2:14][CH2:15][CH2:16][OH:17])[C:6]1[CH:11]=[CH:10][C:9]([N:12]=O)=[CH:8][CH:7]=1.Cl.C(=O)([O-])[O-].[Na+].[Na+]>CO.[Fe]>[OH:17][CH2:16][CH2:15][CH2:14][N:5]([CH2:4][CH2:3][CH2:2][OH:1])[C:6]1[CH:11]=[CH:10][C:9]([NH2:12])=[CH:8][CH:7]=1

Participants

6

Reactant 3

HCID 313Hydrochloric AcidHCID 10340Sodium CarbonateHCID 18692816HCID 18692816, compound

Product 1

HCID 18692792HCID 18692792, compound

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 887MethanolSolvent

Procedure

Iron powder (6.72 g), N,N-bis(3-hydroxypropyl)-4- nitrosoaniline (10 g) and hydrochloric acid(20 cm3) in methanol (120 cm3) were refluxed for 2 hrs. The resulting mixture was made alkaline with sodium carbonate, filtered and the solvent removed to leave N,N-bis(3-hydroxypropyl)-4-aminoaniline as a brown solid.

Workup

  1. filtrationfiltered
  2. customthe solvent removed

Sources & evidence

ORD record
ord-c0cc163d9f1d4fd68c811117e8a2e0f9
Source dataset
uspto-grants-2000_03
Patent number
US06037309

Reaction notes

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