Methylamine → HCID 86754449, compound

HRID 1636958Notes

Reaction equation

HRID 1636958 reaction equation
[CH3:1][NH2:2].[CH3:3][O:4][N:5]=[C:6]([C:26](=[N:28][O:29][CH3:30])[CH3:27])[C:7](=[N:9][O:10][CH2:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=1[CH2:18][O:19][N:20]=[CH:21][C:22]([O:24]C)=O)[CH3:8]>O1CCCC1>[CH3:1][NH:2][C:22](=[O:24])[CH:21]=[N:20][O:19][CH2:18][C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=1[CH2:11][O:10][N:9]=[C:7]([CH3:8])[C:6](=[N:5][O:4][CH3:3])[C:26](=[N:28][O:29][CH3:30])[CH3:27]

Participants

4

Reactant 2

HCID 6329MethylamineHCID 86754450HCID 86754450, compound

Product 1

HCID 86754449HCID 86754449, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

2 ml of 40% strength aqueous methylamine solution are added to a solution of 0.6 g (1.5 mmol) of methyl (2-(2,3-bismethoxyimino-1-methylbutylideneaminooxymethyl)phenyl]methoxyiminoacetate in 10 ml of tetrahydrofuran, and the mixture is stirred for 12 hours at room temperature. For working up, the reaction mixture is evaporated in vacuo, taken up in 20 ml of diethyl ether, washed using 20 ml of water, dried over sodium sulfate and evaporated in vacuo. This gives 0.6 g (98%) of an oil.

Workup

  1. customthe reaction mixture is evaporated in vacuo
  2. washwashed
  3. dry with materialdried over sodium sulfate
  4. customevaporated in vacuo

Sources & evidence

ORD record
ord-93eb55d7306648e8b8c32d54ffe2e575
Source dataset
uspto-grants-2000_03
Patent number
US06037378

Reaction notes

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