Azobisisobutyronitrile → Styrene

HRID 1637148Notes

Reaction equation

HRID 1637148 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]1(=[O:15])[O:14][C:12](=[O:13])[CH:11]=[CH:10]1.C[CH:17]([S:20]([OH:23])(=[O:22])=[O:21])[CH2:18][CH3:19].[C:24]([NH2:28])(=[O:27])[CH:25]=[CH2:26].N(C(C)(C)C#N)=N[C:31](C)(C)C#N>CN(C)C=O>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:12]1(=[O:13])[O:14][C:9](=[O:15])[CH:10]=[CH:11]1.[C:24]([NH:28][C:18]([CH3:19])([CH3:31])[CH2:17][S:20]([OH:23])(=[O:21])=[O:22])(=[O:27])[CH:25]=[CH2:26]

Participants

8

Reactant 4

HCID 6547AzobisisobutyronitrileHCID 7501StyreneHCID 7923Maleic AnhydrideHCID 21871899HCID 21871899, compound

Product 3

HCID 7501StyreneHCID 7923Maleic AnhydrideHCID 653602-Acrylamido-2-methyl-1-propanesulfonic acid

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

A reactor equipped with a stirrer, a thermometer and a reflux condenser was charged with 100 parts of dimethylformamide, 40 parts of styrene, 40 parts of maleic anhydride and 20 parts of acrylamide methylpropanesulfonic acid. After dissolution, 5 parts of azobisisobutyronitrile was added to carry out reaction at 80° C.-100° C. for 4 hours, giving a copolymer of styrene, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. The copolymer was isolated by reprecipitation with isopropyl alcohol and dried under reduced pressure.

Workup

  1. customA reactor equipped with a stirrer
  2. additionwas added
  3. customreaction at 80° C.-100° C. for 4 hours

Sources & evidence

ORD record
ord-af6ada63717a44258857a860b91753f0
Source dataset
uspto-grants-2000_03
Patent number
US06040054

Reaction notes

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