HRID1645205

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID253877

Potassium bromide

BrK

结构：c1ccc(CN(Cc2nc3ccccc3[nH]2)Cc2nc3ccccc3[nH]2)cc1

HCID21107922

未命名化合物

结构：[Cl-].[Cl-].[Cl-].[Cr+3].c1ccc2[nH]c(CNCc3nc4ccccc4[nH]3)nc2c1

HCID86638460

未命名化合物

PRODUCTS

生成物

结构：[Cl-].[Cl-].[Cl-].[Cr+3].c1ccc(CN(Cc2nc3ccccc3[nH]2)Cc2nc3ccccc3[nH]2)cc1

HCID86638462

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

3d was synthesised by an analogous procedure to that described for 3a using 2d (0.63 g, 1.73 mmol) and CrCl3(THF)3 (0.65 g, 1.73 mmol). Yield 0.79 g (88%). Anal. Calc. for C23H21Cl3CrN5 (in %): C, 52.54; H, 4.03; N, 13.32. Found C, 52.43; H, 4.03; N, 13.23. IR (KBr, cm−1), υ 3255 (NH, s), υ 1617-1550 (ArC═C, C═N, m), δ 1454, 1477, 1496 (N—H, s, m), υ 1276 (CN, s), δ 749 (CH, s). UV-VIS (DMF, 298 K): λmax/nm (εmax/dm3 mol−1 cm−1)=462 (162), 665 (75), 726 (shoulder). +FAB-MS: (m/z): 489 ([M-Cl]+), 454 ([M-2Cl]), μμeff·=4.00 MB.