HRID1645207

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID253877

Potassium bromide

BrK

结构：CC(C)N(Cc1nc2ccccc2[nH]1)Cc1nc2ccccc2[nH]1

HCID66775679

未命名化合物

结构：[Cl-].[Cl-].[Cl-].[Cr+3].c1ccc2[nH]c(CNCc3nc4ccccc4[nH]3)nc2c1

HCID86638460

未命名化合物

PRODUCTS

生成物

结构：CC(C)N(Cc1nc2ccccc2[nH]1)Cc1nc2ccccc2[nH]1.[Cl-].[Cl-].[Cl-].[Cr+3]

HCID86638463

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

3f was synthesised by an analogous procedure to that described for 3a using 2f (0.432 g, 1.35 mmol) and CrCl3(THF)3 (0.51 g, 1.35 mmol). Yield 1.20 g (84%). Anal. Calc. for C19H21Cl3CrN5 (in %): C, 47.77; H, 4.43; N, 14.66. Found C, 47.87; H, 4.35; N, 14.46. IR (KBr, cm−1), υ 3227 (NH, s), υ 1623-1550 (ArC═C, C═N, m), δ 1455, 1478, 1497 (N—H, s, m), υ 1275 (CN, m), δ 753 (CH, s). UV-VIS (DMF, 298 K): λmax/nm=459, 704, 731 (shoulder). +FAB-MS: (m/z): 441 ([M-Cl]+), 406 ([M-2Cl]), 320 ([M-CrCl3]). μeff·=3.46 MB.