Ethyl Acetate → HCID 86739105, compound

HRID 1648795Notes

Reaction equation

HRID 1648795 reaction equation
[CH:1]([N:4](SSN(C(C)C)S(C1C=CC(C)=CC=1)(=O)=O)[S:5](C1C=CC(C)=CC=1)(=O)=O)(C)C.ClCl.[S:33](Cl)(Cl)(=[O:35])=[O:34].CN[CH:40]=[N:41][C:42]1[CH:47]=[CH:46][C:45]([CH3:48])=[CH:44][C:43]=1[CH3:49].CNC=[N:53][C:54]1[CH:59]=[C:58](Cl)[CH:57]=[CH:56][C:55]=1C.[C:62](OCC)(=O)C>>[C:42]1([N:41]=[CH:40][CH2:1][NH:4][S:5][N:53]([C:54]2[CH:55]=[CH:56][CH:57]=[CH:58][CH:59]=2)[S:33]([CH3:62])(=[O:35])=[O:34])[CH:47]=[CH:46][C:45]([CH3:48])=[CH:44][C:43]=1[CH3:49]

Participants

7

Reactant 6

HCID 8857Ethyl AcetateHCID 24526ChlorineHCID 24648Sulfuryl chlorideHCID 20481811HCID 20481811, compoundHCID 178484910HCID 178484910, compoundHCID 178484923HCID 178484923, compound

Product 1

HCID 86739105HCID 86739105, compoundYield 14%

Procedure

Following the procedure for Example 2, but substituting N,N'-dithiobis[N-pheylmethanesulfonamide] for N,N'-dithiobis-[N-isopropyl-p-toluenesulfonamide], chlorine for sulfuryl chloride, and N-methyl-N'-2,4-xylylformamidine for N-methyl-N'-(4-chloro-o-tolyl) formamidine, the product is prepared. The product is recrytallized from ethyl acetate to give 2.0 g. (14% yield) of N-[[[N-2,4-xylylformimidoyl]methylamino]thio]-N-phenylmethanesulfonamide as white crystals, mp. 120°-121.5°.

Workup

  1. customthe product is prepared
  2. customto give 2.0 g

Sources & evidence

ORD record
ord-07d2941ceb6a4c18abc986f46e81cbbd
Source dataset
uspto-grants-1983_11
Patent number
US04413013

Reaction notes

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