Sodium Bicarbonate → HCID 23668221, compound

HRID 1649357Notes

Reaction equation

HRID 1649357 reaction equation
[CH3:1][Si:2]([CH3:28])([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH2:3][CH2:4][CH2:5][NH:6][C:7]1[CH:15]=[CH:14][C:10]([C:11]([OH:13])=[O:12])=[CH:9][CH:8]=1.C(=O)(O)[O-].[Na+:33]>C(O)C>[CH3:28][Si:2]([CH3:1])([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH2:3][CH2:4][CH2:5][NH:6][C:7]1[CH:8]=[CH:9][C:10]([C:11]([O-:13])=[O:12])=[CH:14][CH:15]=1.[Na+:33]

Participants

4

Reactant 2

HCID 516892Sodium BicarbonateHCID 13251037HCID 13251037, compound

Product 1

HCID 23668221HCID 23668221, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

To a solution of 6.79 g (16.7 mmol) of 4-(4,4-dimethyl-4-sila-hexadecylamino)benzoic acid in 10 ml of ethanol is added an aqueous solution of 1.5 g (17.8 mmol) of sodium bicarbonate (in about 50 ml of water). The mixture is heated to 60° and the resultant clear solution evaporated, under vacuum, to obtain the title product as a white crystalline solid, m.p. above 300°.

Workup

  1. temperatureThe mixture is heated to 60°
  2. customthe resultant clear solution evaporated, under vacuum

Sources & evidence

ORD record
ord-f976c2686f624b64a0855095cc4a7e21
Source dataset
uspto-grants-1983_11
Patent number
US04416876

Reaction notes

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