HRID165212

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID961

Hydroxide

HO-

HCID1049

Pyridine

C5H5N

HCID6344

Dichloromethane

CH2Cl2

HCID23938

Palladium

HCID24404

Phosphine

H3P

HCID28486

Lithium ion

Li+

HCID67749

Trifluoromethanesulfonic anhydride

C2F6O5S2

HCID254003

未命名化合物

结构：O=S(=O)(Oc1ccc2ccccc2c1-c1c(OS(=O)(=O)C(F)(F)F)ccc2ccccc12)C(F)(F)F

HCID389883

Methanesulfonic acid, trifluoro-, (1,1'-binaphthalene)-2,2'-diyl ester

C22H12F6O6S2

HCID2755260

1-(1-Naphthyl)-2-naphthol

C20H14O

结构：O=P(c1ccccc1)(c1ccccc1)c1ccc2ccccc2c1-c1c(OS(=O)(=O)C(F)(F)F)ccc2ccccc12

HCID10438576

未命名化合物

PRODUCTS

生成物

结构：O=P(c1ccccc1)(c1ccccc1)c1ccc2ccccc2c1-c1c(O)ccc2ccccc12

HCID4417985

2'-diphenylphosphinyl-2-hydroxy-1,1'-binaphthyl

C32H23O2P

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e30b068c0ef54d95834d79bc39d1f503
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[CH2:131]([Cl:132])[Cl:133].[F:22][C:23]([S:24]([O:25][S:26]([C:27]([F:28])([F:29])[F:30])(=[O:31])=[O:32])(=[O:33])=[O:34])([F:35])[F:36].[F:37][C:38]([F:39])([F:40])[S:41]([O:42][c:43]1[cH:44][cH:45][c:46]2[c:47]([cH:48][cH:49][cH:50][cH:51]2)[c:52]1-[c:53]1[c:54]2[c:55]([cH:56][cH:57][cH:58][cH:59]2)[cH:60][cH:61][c:62]1[O:63][S:64]([C:65]([F:66])([F:67])[F:68])(=[O:69])=[O:70])(=[O:71])=[O:72].[Li+:129].[OH-:130].[PH3:134].[Pd:135].[c:1]1(-[c:2]2[c:3]3[c:4]([cH:5][cH:6][cH:7][cH:8]3)[cH:9][cH:10][cH:11]2)[c:12]([OH:13])[cH:14][cH:15][c:16]2[c:17]1[cH:18][cH:19][cH:20][cH:21]2.[c:73]1([PH:74](=[O:75])[c:76]2[cH:77][cH:78][cH:79][cH:80][cH:81]2)[cH:82][cH:83][cH:84][cH:85][cH:86]1.[c:87]1([P:93](=[O:94])([c:95]2[c:96](-[c:105]3[c:106]([O:115][S:116]([C:117]([F:118])([F:119])[F:120])(=[O:121])=[O:122])[cH:107][cH:108][c:109]4[cH:110][cH:111][cH:112][cH:113][c:114]34)[c:97]3[cH:98][cH:99][cH:100][cH:101][c:102]3[cH:103][cH:104]2)[c:123]2[cH:124][cH:125][cH:126][cH:127][cH:128]2)[cH:88][cH:89][cH:90][cH:91][cH:92]1.[cH:136]1[cH:137][cH:138][n:139][cH:140][cH:141]1>>[c:87]1([P:93](=[O:94])([c:95]2[c:96](-[c:105]3[c:106]([OH:115])[cH:107][cH:108][c:109]4[cH:110][cH:111][cH:112][cH:113][c:114]34)[c:97]3[cH:98][cH:99][cH:100][cH:101][c:102]3[cH:103][cH:104]2)[c:123]2[cH:124][cH:125][cH:126][cH:127][cH:128]2)[cH:88][cH:89][cH:90][cH:91][cH:92]1