Hydrochloric Acid → HCID 10923601, compound

HRID 1655651Notes

Reaction equation

HRID 1655651 reaction equation
C([O:4][CH2:5][N:6]([N+:22]([O-:24])=[O:23])[CH2:7][N:8]([N+:19]([O-:21])=[O:20])[CH2:9][N:10]([N+:16]([O-:18])=[O:17])[CH2:11][O:12]C(=O)C)(=O)C.Cl>>[OH:12][CH2:11][N:10]([N+:16]([O-:18])=[O:17])[CH2:9][N:8]([N+:19]([O-:21])=[O:20])[CH2:7][N:6]([N+:22]([O-:24])=[O:23])[CH2:5][OH:4]

Participants

3

Reactant 2

HCID 313Hydrochloric AcidHCID 84237Methanol, ((nitroimino)bis(methylene(nitroimino)))bis-, diacetate (ester) (9CI)

Product 1

HCID 10923601HCID 10923601, compound

Procedure

To 6.7g of 1,7-diacetoxy-2,4,6-trinitro-2,4,6-triazaheptane (18.9 mmol) was added 33 ml of 30% aqueous HCl. The mixture was then stirred for 48 hours at room temperature. The solid was collected by suction filtration through a sintered glass funnel, washed with distilled water, and dried in vacuo. Collected was 3.9 g (75%); melting point 134°-138° C.; 1H NMR spectrum (d3 -acetonitrile): δ 5.40 and 5.87.

Workup

  1. filtrationThe solid was collected by suction filtration through a sintered glass funnel
  2. washwashed with distilled water
  3. customdried in vacuo
  4. customCollected

Sources & evidence

ORD record
ord-169a57c9243044c8bcbdee75718bc2f1
Source dataset
uspto-grants-1993_10
Patent number
US05250730

Reaction notes

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