Dimethyl Sulfide → HCID 11745097, compound

HRID 1658699Notes

Reaction equation

[CH3:1][S:2][CH3:3].[CH3:4][S:5]([O:8]C)(=[O:7])=[O:6]>>[CH3:4][S:5]([O-:8])(=[O:7])=[O:6].[CH3:1][S+:2]([CH3:4])[CH3:3]

Participants

Reactant 2

HCID 1068Dimethyl Sulfide

HCID 4156Methyl Methanesulfonate

Product 1

HCID 11745097HCID 11745097, compound

Procedure

A mixture of 1.24 g of dimethylsulfide and 2.20 g of methyl methanesulfonate was allowed to stand for three days at room temperature. The crystals which deposited were collected by filtration, washed with diethyl ether and dried. By this procedure crystals of S,S,S-trimethylsulfonium methanesulfonate were obtained. When this product was recrystallized, it had a melting point of 193.0° to 195.0°C.

Workup

filtrationThe crystals which deposited were collected by filtration
washwashed with diethyl ether
customdried

Sources & evidence

ORD record: ord-ddda0e3cdc3442c79f6f56766ae37a15
Source dataset: uspto-grants-1976_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US03966720

Reaction notes

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