Isopropanol → Aluminum isopropoxide

HRID 1659651Notes

Reaction equation

HRID 1659651 reaction equation
[Al:1].C(Cl)(Cl)(Cl)Cl.[CH:7]([OH:10])([CH3:9])[CH3:8].[O:11](C1C=C(C=CC=1)C=O)[C:12]1[CH:17]=CC=C[CH:13]=1>C1(C)C=CC=CC=1>[CH3:8][CH:7]([O-:10])[CH3:9].[CH3:13][CH:12]([O-:11])[CH3:17].[CH3:8][CH:7]([O-:10])[CH3:9].[Al+3:1]

Participants

6

Reactant 4

HCID 3776IsopropanolHCID 5943Carbon TetrachlorideHCID 382843-PhenoxybenzaldehydeHCID 5359268Aluminum

Product 1

HCID 11143Aluminum isopropoxide

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent3×

Procedure

From a mixture of 16.33 g. of aluminum chips, 100 ml. of toluene and 0.1 g. of mercuric chloride and a solution of 11 ml. of carbontetrachloride and 140 ml. of isopropyl alcohol a solution of aluminum isopropylate in toluene is prepared. A solution of 198.2 g. of 3-phenoxybenzaldehyde in 70 ml. of toluene is added, and the reaction mixture is kept at 45° to 50° C. for 3 hours.

Workup

  1. additionFrom a mixture of 16.33 g

Sources & evidence

ORD record
ord-46352ac1fe69439d81ea25b3a71806d6
Source dataset
uspto-grants-1981_12
Patent number
US04304938

Reaction notes

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