Oxalyl chloride → HCID 86634424, compound

HRID 1661215Notes

Reaction equation

HRID 1661215 reaction equation
[C:1]1([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH:6]=[CH:5][CH:4]=[C:3]([N:7]2[CH:11]=[C:10]([C:12](O)=[O:13])[N:9]=[CH:8]2)[CH:2]=1.C(Cl)(=O)C([Cl:24])=O>>[C:1]1([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)[CH:6]=[CH:5][CH:4]=[C:3]([N:7]2[CH:11]=[C:10]([C:12]([Cl:24])=[O:13])[N:9]=[CH:8]2)[CH:2]=1

Participants

3

Reactant 2

HCID 65578Oxalyl chlorideHCID 16128907HCID 16128907, compound

Product 1

HCID 86634424HCID 86634424, compound

Procedure

A solution of 10a (2.0 g, 7.6 mmol) in oxalyl chloride (30 ml) was stirred at 60° C. overnight. Excess oxalyl chloride was removed under reduced pressure to leave 11a.

Workup

  1. customExcess oxalyl chloride was removed under reduced pressure

Sources & evidence

ORD record
ord-8d43afc4219e40f18e6c093f25feee0e
Source dataset
uspto-grants-2011_10
Patent number
US08030339B2

Reaction notes

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