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HRID1662469

反应详情

EQUATION

反应方程式

HRID 1662469 的结构方程式

REACTANTS

反应物

2
结构：Cc1ccc(S(=O)(=O)[O-])cc1.c1cc[nH+]cc1
HCID466102

未命名化合物

结构：COc1ccc(F)c(-c2ccc(CO[Si](C)(C)C(C)(C)C)cc2C2(OC)CCCC2)c1
HCID57706027

未命名化合物

PRODUCTS

生成物

1
结构：COc1ccc(F)c(-c2ccc(CO)cc2C2(OC)CCCC2)c1
HCID57706279

未命名化合物

收率 61%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

To a solution of 66.68E (66 mg, 168 μmol) in MeOH, was added PPTS (11 mg, 45 μmol), and the mixture was stirred for 16 hours. Solvent was then removed in vacuo to give a residue which was purified by Combiflash chromatography to give the product as an oil (30 mg, 61%). MS ESI m/e: 331.2 (M+H)+.

WORKUP

后处理

  1. customSolvent was then removed in vacuo
  2. customto give a residue which
  3. customwas purified by Combiflash chromatography