HRID166995

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID923

Sodium ion

Na+

HCID7397

p-Toluenesulfonyl chloride

C7H7ClO2S

HCID9223

2,3-Benzofuran

C8H6O

HCID33558

Azide

N3-

HCID85570

Tosylate

C7H7O3S-

结构：COc1cc2c(c(C(C)(C)C)c1)OC(COS(=O)(=O)c1ccc(C)cc1)C2

HCID86599179

未命名化合物

PRODUCTS

生成物

结构：COc1cc2c(c(C(C)(C)C)c1)OC(CN=[N+]=[N-])C2

HCID86599178

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-ce663dc01db74091b5c5be39da296de1
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[CH3:21][c:22]1[cH:23][cH:24][c:25]([S:26]([O:27][CH2:32][CH:33]2[O:34][c:35]3[c:36]([cH:38][c:39]([O:46][CH3:47])[cH:40][c:41]3[C:42]([CH3:43])([CH3:44])[CH3:45])[CH2:37]2)(=[O:28])=[O:29])[cH:30][cH:31]1.[N-:60]=[N+:61]=[N-:62].[Na+:59].[O-:48][S:49]([c:50]1[cH:51][cH:52][c:53]([CH3:54])[cH:55][cH:56]1)(=[O:57])=[O:58].[c:10]1([CH3:11])[cH:12][cH:13][c:14]([S:15]([Cl:16])(=[O:17])=[O:18])[cH:19][cH:20]1.[o:1]1[c:2]2[cH:3][cH:4][cH:5][cH:6][c:7]2[cH:8][cH:9]1>>[CH2:32]([CH:33]1[O:34][c:35]2[c:36]([cH:38][c:39]([O:46][CH3:47])[cH:40][c:41]2[C:42]([CH3:43])([CH3:44])[CH3:45])[CH2:37]1)[N:60]=[N+:61]=[N-:62]