Methylamine → 4-tert-Butyl-N-methyl-2,6-dinitroaniline

HRID 1678835Notes

Reaction equation

HRID 1678835 reaction equation
[CH3:1][NH2:2].[N+:3]([C:6]1[CH:11]=[C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])[CH:9]=[C:8]([N+:16]([O-:18])=[O:17])[C:7]=1Cl)([O-:5])=[O:4]>>[CH3:1][NH:2][C:7]1[C:6]([N+:3]([O-:5])=[O:4])=[CH:11][C:10]([C:12]([CH3:15])([CH3:14])[CH3:13])=[CH:9][C:8]=1[N+:16]([O-:18])=[O:17]

Participants

3

Reactant 2

HCID 6329MethylamineHCID 751764-tert-Butyl-2,6-dinitrochlorobenzene

Product 1

HCID 6172794-tert-Butyl-N-methyl-2,6-dinitroaniline

Procedure

Following the above procedure, two grams of 40% aqueous solution of methyl amine was reacted with 2.6 grams of 2,6-dinitro-4-t-butyl-chlorobenzene to give N-methyl-2,6-dinitro-4-t-butylaniline as orange needles melting at 129°-130° C.

Sources & evidence

ORD record
ord-5df2be3711724d7dbe255d1a415c0583
Source dataset
uspto-grants-1978_03
Patent number
US04077795

Reaction notes

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