Methylamine → HCID 59896620, compound

HRID 1682229Notes

Reaction equation

HRID 1682229 reaction equation
[Cl:1][C:2]1[N:7]=[CH:6][C:5]([CH2:8][NH:9][C:10](SC)=[CH:11][N+:12]([O-:14])=[O:13])=[CH:4][CH:3]=1.O.[NH2:18][NH2:19].CSC(NCC1C=NC=CC=1)=C[N+]([O-])=O.CN>>[Cl:1][C:2]1[N:7]=[CH:6][C:5]([CH2:8][NH:9][C:10]([NH:18][NH2:19])=[CH:11][N+:12]([O-:14])=[O:13])=[CH:4][CH:3]=1

Participants

5

Reactant 4

HCID 6329MethylamineHCID 24654Hydrazine hydrate (1:1)HCID 70155832HCID 70155832, compoundHCID 855929321-(6-Chloro-3-pyridylmethyl)amino-1-methylthio-2-nitroethylene

Product 1

HCID 59896620HCID 59896620, compound

Procedure

The reaction procedure of Example 3 was repeated except that 1-(6-chloro-3pyridylmethyl)amino-1-methylthio-2-nitroethylene and hydrazine hydrate were used in lieu of 1-methylthio-1-(3-pyridylmethyl)amino-2-nitroethylene and aqueous methylamine solution, respectively. The procedure gave the title compound as pale yellow crystals.

Workup

  1. customThe reaction procedure of Example 3

Sources & evidence

ORD record
ord-13269a2322b64f2c9983d5061198c84f
Source dataset
uspto-grants-1992_12
Patent number
US05175301

Reaction notes

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