Palladium Chloride → Palladium triflate

HRID 1682776Notes

Reaction equation

HRID 1682776 reaction equation
Cl[Pd:2]Cl.[OH:4][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:7])=[O:6]>C(Cl)Cl>[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4].[Pd+2:2].[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4]

Participants

4

Reactant 2

HCID 24290Palladium ChlorideHCID 62406Trifluoromethanesulfonic acid

Product 1

HCID 11603820Palladium triflate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

PdCl2 (1.0 g, 5.6 mmol) was slurried in CH2Cl2 (20 mL) and triflic acid (1.7 g, 11.3 mmol) was added dropwise. The mixture was stirred at room temperature overnight. The solvent was removed and 0.9 g of rust color solid was collected. 19F NMR (CDCl3): δ-5 78.5.

Workup

  1. customThe solvent was removed
  2. custom0.9 g of rust color solid was collected

Sources & evidence

ORD record
ord-f53ff08b482544a3899a442bed6f5ef3
Source dataset
uspto-grants-1997_06
Patent number
US05635585

Reaction notes

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