Hydrogen Bromide → HCID 86750952, compound

HRID 1683433Notes

Reaction equation

[F:1][C:2]([F:30])([CH2:25][C:26]([F:29])([F:28])[F:27])[C:3]([F:24])([F:23])[O:4][CH2:5][C:6]1([CH2:10][O:11][C:12]([F:22])([F:21])[C:13]([F:20])([F:19])[CH2:14][C:15]([F:18])([F:17])[F:16])[CH2:9][O:8][CH2:7]1.[BrH:31]>>[Br:31][CH2:7][C:6]([CH2:10][O:11][C:12]([F:22])([F:21])[C:13]([F:20])([F:19])[CH2:14][C:15]([F:18])([F:17])[F:16])([CH2:5][O:4][C:3]([F:24])([F:23])[C:2]([F:30])([F:1])[CH2:25][C:26]([F:29])([F:28])[F:27])[CH2:9][OH:8]

Participants

Reactant 2

HCID 260Hydrogen Bromide

HCID 86750950HCID 86750950, compound

Product 1

HCID 86750952HCID 86750952, compoundYield 89.1%

Procedure

In a manner similar to that described above, 3,3-bis(heptafluorobutoxymethyl)oxetane (250.0 g, 0.52 mole) was reacted with 48% HBr (131.7 g, 0.78 mole) to give 260.9 g (89.1%) of 3-bromo-2,2-bis(heptafluorobutoxymethyl)-1-propanol, a clear oil: 1H NMR (CDCl3) 3.49 (s, 2H), 3.65 (s, 4H), 3.69 (s, 2H), and 3.95 (t, J=13.3 Hz, 2H); Anal. Calcd for C13H13BrF14O3 : C, 27.72; H, 2.33; Br, 14.19; Found: C, 27.73; H, 2.27; Br, 14.09.

Sources & evidence

ORD record: ord-08001a8e04904b8dadeb6e5a1ffcc003
Source dataset: uspto-grants-1997_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05637772

Reaction notes

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