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HRID1701272

反应详情

EQUATION

反应方程式

HRID 1701272 的结构方程式

REACTANTS

反应物

4
结构：C=NO
HCID6350

Nitrone

CH3NO

结构：O=[N+]([O-])c1ccccc1
HCID7416

Nitrobenzene

C6H5NO2

结构：Cc1cccc(C)n1
HCID7937

2,6-Dimethylpyridine

C7H9N

结构：CCN(CC)c1ccc(N=Nc2c(I)cc([N+](=O)[O-])cc2[N+](=O)[O-])c(NC(C)=O)c1
HCID104720

Acetamide, N-[5-(diethylamino)-2-[(2-iodo-4,6-dinitrophenyl)azo]phenyl]-

C18H19IN6O5

PRODUCTS

生成物

1
结构：CCN(CC)c1ccc(N=Nc2c(C#N)cc([N+](=O)[O-])cc2[N+](=O)[O-])c(NC(C)=O)c1
HCID90383

N-(2-((2-Cyano-4,6-dinitrophenyl)azo)-5-(diethylamino)phenyl)acetamide

C19H19N7O5

AUXILIARIES

试剂、催化剂与溶剂

1
结构：[Cu][I]
催化剂HCID24350

Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

CuI

CONDITIONS

反应条件

温度
95 °C

PROCEDURE

实验过程

A stirred mixture of 3-acetylamino-4-(2'-iodo-4',6'-dinitrophenylazo)-N,N-diethylaniline (4.8 parts), copper (I) iodide (2.0 parts), formaldoxime trimer (1.75 parts), 2,6-lutidine (2.15 parts), and nitrobenzene (150 parts) was heated to 95° C. for 10 hours when thin layer chromatography showed reaction to be complete. Isolation of the product as in Example 1 gave 3-acetylamino 4-(2'-cyano-4',6'-dinitrophenylazo)-N,N-diethylaniline (infra red spectrum identical with that of authentic material).

WORKUP

后处理

  1. customreaction