Methane → HCID 131712827, compound

HRID 1702836Notes

Reaction equation

HRID 1702836 reaction equation
[Cl:1][C:2]1[C:11]([CH3:12])=[N:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[N:3]=1.C.[CH2:14]([NH:16][C:17]([NH:19][CH2:20][CH3:21])=[S:18])[CH3:15]>CC(C)=O>[ClH:1].[CH3:12][C:11]1[C:2]([S:18][C:17](=[N:16][CH2:14][CH3:15])[NH:19][CH2:20][CH3:21])=[N:3][C:4]2[C:9]([N:10]=1)=[CH:8][CH:7]=[CH:6][CH:5]=2

Participants

5

Reactant 3

HCID 297MethaneHCID 2362762-Chloro-3-methylquinoxalineHCID 2735009N,N'-Diethylthiourea

Product 1

HCID 131712827HCID 131712827, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent2×

Procedure

2-Chloro-3-methylquinoxaline (15.0 g., 0.084 mole) was dissolved in 225 ml. of acetone, treated with Norit and filtered. The filtrate was added to 11.11 g. (0.084 mole) of 1,3-diethylthiourea in 175 ml. of acetone and the mixture was stirred at room temperature for 51/2 hours. The solid which separated was filtered and washed well with acetone, then with ether and dried to give 18.12 g. (69.7%) of product, m.p. 121.5°-122°.

Workup

  1. filtrationfiltered
  2. additionThe filtrate was added to 11.11 g
  3. customThe solid which separated
  4. filtrationwas filtered
  5. washwashed well with acetone
  6. dry with materialwith ether and dried
  7. customto give 18.12 g

Sources & evidence

ORD record
ord-8b9274d435ee4d80b162beb49e4a7648
Source dataset
uspto-grants-1982_09
Patent number
US04349674

Reaction notes

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