Adipic Acid → HCID 86738146, compound

HRID 1703071Notes

Reaction equation

HRID 1703071 reaction equation
[Si:1]([O-:5])([O-:4])([O-:3])[O-:2].[Na+:6].[Na+].[Na+].[Na+].[C:10](O)(=O)[CH2:11][CH2:12][CH2:13]CC(O)=O.C=CC=C.[Na].OO.C(S)CCCCCCCCCCC>>[Si:1]([O-:5])([O-:4])([O-:3])[O-:2].[Na+:6].[Na+:6].[Na+:6].[Na+:6].[CH2:10]=[CH:11][CH:12]=[CH2:13]

Participants

7

Reactant 6

HCID 196Adipic AcidHCID 784Hydrogen PeroxideHCID 78451,3-ButadieneHCID 81951-DodecanethiolHCID 26051Sodium orthosilicateHCID 5360545Sodium

Product 1

HCID 86738146HCID 86738146, compound

Procedure

About 30 parts by weight of an aqueous sodium silicate solution containing about 10% Na2O and 15% SiO2, 1 part by weight of adipic acid, 20 parts by weight of butadiene, 0.5 parts by weight of sodium salt of fatty acids, 0.05 to 0.1 parts by weight of ferric sulfate, 0.1 parts by weight of hydrogen peroxide, 0.01 parts by weight of benzoxyl peroxide and 0.1 parts by weight of lauryl mercaptan are mixed in a closed system at ambient to 50° C. while agitating at about 0.40 to 6 psiq for 30 to 120 minutes; then the mixture is heated to 70° to 100° C. at ambient pressure for 10 to 30 minutes. The reaction is complete within 24 hours thereby producing an emulsion of poly(sodium silicate-butadiene) copolymer.

Workup

  1. additionare mixed in a closed system at ambient to 50° C.
  2. temperaturethen the mixture is heated to 70° to 100° C. at ambient pressure for 10 to 30 minutes
  3. waitThe reaction is complete within 24 hours

Sources & evidence

ORD record
ord-591ce82c67664a9a8688b508f6b9cdf6
Source dataset
uspto-grants-1982_09
Patent number
US04350775

Reaction notes

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