Isopropanol → HCID 131728026, compound

HRID 1710299Notes

Reaction equation

HRID 1710299 reaction equation
[C:1]([O:5][C:6]([C:12]([O:15][C:16](=[C:18]([F:20])[F:19])[F:17])([F:14])[F:13])([C:8]([F:11])([F:10])[F:9])[F:7])([F:4])([F:3])[F:2].[CH:21]([OH:24])([CH3:23])[CH3:22]>>[C:1]([O:5][C:6]([C:12]([O:15][CH:16]([C:18]([C:21]([OH:24])([CH3:23])[CH3:22])([F:19])[F:20])[F:17])([F:13])[F:14])([C:8]([F:11])([F:10])[F:9])[F:7])([F:4])([F:3])[F:2]

Participants

3

Reactant 2

HCID 3776IsopropanolHCID 125416801,1,1,2,3,3-Hexafluoro-2-(trifluoromethoxy)-3-[(trifluorovinyl)oxy]propane

Product 1

HCID 131728026HCID 131728026, compound

Procedure

CF3OCF(CF3)CF2OCFHCF2C(CH3)2OH was prepared by the reaction of CF3OCF(CF3)CF2OCF═CF2 (52.9 g, 0.16 mol) with isopropanol (202 g, 3.37 mol) using LUPEROX 575 (11.4 g) as free radical initiator at 75° C. The resulting product reaction mixture was distilled and the distillation fraction of b.r.=161-166° C. used in the next step.

Workup

  1. customat 75° C
  2. customThe resulting product reaction mixture
  3. distillationwas distilled
  4. custom=161-166° C.

Sources & evidence

ORD record
ord-806660a066c04fc5a0752035123d4a31
Source dataset
uspto-grants-2010_09
Patent number
US07790312B2

Reaction notes

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