p-Chlorothiophenol → HCID 53887707, compound

HRID 1720241Notes

Reaction equation

HRID 1720241 reaction equation
Cl[C:2](=[N:6][NH:7][C:8]1[CH:13]=[CH:12][C:11]([Cl:14])=[CH:10][CH:9]=1)[C:3](=[O:5])[CH3:4].[Cl:15][C:16]1[CH:21]=[CH:20][C:19]([SH:22])=[CH:18][CH:17]=1>C(N(CC)CC)C>[Cl:15][C:16]1[CH:21]=[CH:20][C:19]([S:22][C:2](=[N:6][NH:7][C:8]2[CH:13]=[CH:12][C:11]([Cl:14])=[CH:10][CH:9]=2)[C:3](=[O:5])[CH3:4])=[CH:18][CH:17]=1

Participants

4

Reactant 2

HCID 7815p-ChlorothiophenolHCID 2771515Propanehydrazonoyl chloride, N-(4-chlorophenyl)-2-oxo-

Product 1

HCID 53887707HCID 53887707, compoundYield 96%

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

The reaction of 4.47 g of 1-chloro-1-[(4-chlorophenyl) hydrazono]-2-propanone with 3.43 g of 4-chlorothiophenol and 3.36 ml of triethylamine as Example 11 yielded 6.3 g of 1-[(4-chlorophenyl)thio]-1-[(4-chlorophenyl)hydrazono]-2-propanone, mp 164°-167° C.

Sources & evidence

ORD record
ord-01aed47fbe724b3fa14b01bbbb1871a1
Source dataset
uspto-grants-1996_04
Patent number
US05506228

Reaction notes

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