p-Chlorothiophenol → HCID 53834495, compound

HRID 1720245Notes

Reaction equation

HRID 1720245 reaction equation
Cl[C:2](=[N:6][NH:7][C:8]1[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=1)[C:3](=[O:5])[CH3:4].[Cl:15][C:16]1[CH:21]=[CH:20][C:19]([SH:22])=[CH:18][CH:17]=1.C(N(CC)CC)C>C(O)C>[Cl:15][C:16]1[CH:21]=[CH:20][C:19]([S:22][C:2](=[N:6][NH:7][C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)[C:3](=[O:5])[CH3:4])=[CH:18][CH:17]=1

Participants

5

Reactant 3

HCID 7815p-ChlorothiophenolHCID 8471TriethylamineHCID 2771523Propanehydrazonoyl chloride, N-(4-methylphenyl)-2-oxo-

Product 1

HCID 53834495HCID 53834495, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The reaction of 4.07(0.0193 mol) g of 1-chloro-1-[(4-methylphenyl-)hydrazono]-2-propanone, 3.43 g of 4-chlorothiophenol and 3.36 ml of triethylamine in 40 ml of ethanol as in Example 11 yielded 5.55 g of 1-[(4-chlorophenyl)thio]-1-[(4-methylphenyl)hydrazono]-2-propanone, mp 133°-135.5° C.

Sources & evidence

ORD record
ord-8a29208b87914a71b670467bb7ab1dda
Source dataset
uspto-grants-1996_04
Patent number
US05506228

Reaction notes

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