Thiophenol → HCID 53927081, compound

HRID 1720248Notes

Reaction equation

HRID 1720248 reaction equation
Cl[C:2](=[N:6][NH:7][C:8]1[CH:13]=[CH:12][C:11]([O:14][CH3:15])=[CH:10][CH:9]=1)[C:3](=[O:5])[CH3:4].[C:16]1([SH:22])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1.C(N(CC)CC)C>C(O)C>[C:16]1([S:22][C:2](=[N:6][NH:7][C:8]2[CH:13]=[CH:12][C:11]([O:14][CH3:15])=[CH:10][CH:9]=2)[C:3](=[O:5])[CH3:4])[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1

Participants

5

Reactant 3

HCID 7969ThiophenolHCID 8471TriethylamineHCID 2844936Propanehydrazonoyl chloride, N-(4-methoxyphenyl)-2-oxo-

Product 1

HCID 53927081HCID 53927081, compoundYield 84.7%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The reaction of 392 mg of 1-chloro-1-[(4-methoxyphenyl) hydrazono]-2-propanone, 220 mg of thiophenol and 280 ul of triethylamine in 6 ml of ethanol as in Example 11 yielded 440 mg of 1-[(phenyl)thio]-1-[(4-methoxyphenyl)hydrazono]-2-propanone, mp 120°-123° C.

Sources & evidence

ORD record
ord-5b82f80352b8494abd11902c46fa4986
Source dataset
uspto-grants-1996_04
Patent number
US05506228

Reaction notes

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